Stress corrosion cracking of sensitized type 304 stainless steel in thiosulfate solutions r. The influence of cold work prestraining in the range 2. Stress corrosion cracking of type aisi 304 stainless steel. In this work, hotcell tests and micro structural characterization were performed on type 304 ss from the hexagonal fuel can of the decommissioned ebrii reactor after. Potential and strainrate effects in slow strainrate stress corrosion cracking of type 304 stainless steel in 35 percent magnesium chloride at 120c. The environmental factors that increase the cracking susceptibility include higher temperatures, increased chloride content, lower ph, and higher levels of tensile stress. This paper discuses the stress corrosion cracking observed when slow strain rate tests were run on aisi 304 stainless steel specimens in oxygenated 288 c water. The effect of hydrogen peroxide on the stress corrosion. Stress corrosion cracking of duplex stainless steel scc stress corrosion cracking is a form of corrosion which occurs with a particular combination of factors. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature.
Stress corrosion cracking of sensitized type 304 stainless. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. In recent years, failures of reactor internal components have been observed after the components have reached neutron fluence levels 5 x 10 20 ncm2 e 1 mev. The material used in the present study is 304 stainless steel, the chemical composition of it is shown in table i.
Transgranular, intergranular, and granulated stress corrosion cracks were observed. The effects of titanium ion implantation on the stress corrosion cracking scc behaviour of 304 austenitic stainless steel were studied. Stainless steel for hardness and corrosion resistance. Isaacs the stress corrosion cracking of a sensitized type 304 stainless steel has been studied at room temperature using controlled potentials and two concentrations of sodium thiosulfate. Practical solutions by solutions for people, processes and paper. Stress corrosion cracking is a rapid and severe form of stainless steel corrosion. Stainless steels types 304 and 316 can be considered resistant below 80 degc, up to the limit of solubility. Stress corrosion cracking scc of 304 stainless steel ss in hightemperature water was insitu monitored by analyzing acoustic emission ae waveform. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature.
Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k. The elbow was welded with two straight pipes at two ends. Chloride stress corrosion cracking and 316 stainless steel moltenmetal chemical 20 jul 11 07. Transgranular, granulated, and intergranular stress. On the stress corrosion cracking and hydrogen embrittlement. The susceptibility of the hp absorber tubes to intergranular stress corrosion cracking igscc was higher than that of the cp absorber tubes or the cp control blade sheath. Pitting or crevice corrosion can occur on most stainless steel grades.
The general pattern of the observed failures indicates that as nuclear plants age and fluence increases, various apparently nonsensitized. Inhibition of stress corrosion cracking in 304 stainless. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Stainless steel grades, such as the 304 or 316 types are generally. There can be a risk of stress corrosion cracking scc. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. The effect of hydrogen peroxide on stress corrosion crack growth rate of sensitized 304 stainless steel in high temperature water was investigated using a specially designed testing cell which minimizes the decomposition of hydrogen peroxide. The fracture of a stainless steel pipe in a hydrogen manufacturing facility prompted a study of stress corrosion cracking of 304l stainless steel and 1 l4 cr l2 mo low alloy steel in aqueous potassium hydroxide solutions using the slow strain rate technique. However, it can be susceptible to pitting and crevice corrosion in chloride environments. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain. Potential and strain rate effects in slow strain rate stress.
A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Stress corrosion cracking of type 304 austenitic stainless. Several scc modes including transgranular scc tgscc, intergranular scc igscc and mixture of tgscc and igscc were obtained by changing material state and controlling load mode, dissolved. Slow strain rate tests ssrts were conducted on 304 steel in air and in 5 wt% nacl solution. Pdf stress corrosion cracking of 304l stainless steel in. Atmospheric stress corrosion cracking susceptibility of welded and unwelded 304,304l, and 316l austenitic stainless steels commonly used for dry cask storage containers exposed to marine environments. Scc of the 300 series stainless steels is classically transgranular. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. Based on this analysis the leaks were caused by cracks that initiated on the id surface. The type 321 austenitic stainless steel is susceptible to stress corrosion cracking scc in halides similar to type 304 stainless steel. Type 304 stainless steel stress corrosion cracking scc in stainless steels. Unexpected corrosion of stainless steel in high solids black liquor service. Samples were found to fracture in solutions of more than 3% sulfurous acid. Temperatures above ambient and cycling between hot and cold temperatures can make corrosion worse as concentration of chlorides due to evaporation can occur.
Stresscorrosion cracking of sensitized type 304 stainless. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. The influence of copper on the stress corrosion cracking of 304. This research was focused on the failure analysis of a cracked ss304 stainless steel elbow from a chemical plant. A comparison of the behaviour of these steels in the form of tubes with those made of sheets under stress corrosion cracking scc tests was discussed. A key question is the nature of irradiationassisted intergranular cracking at very high dose, i. Effect of halogens and inhibitors on the external stress. Intergranular stress corrosion cracking caused failure of two type304 stainlesssteel outlet nozzles in highpurity heavywater moderator service in nuclear reactors. Stress corrosion cracking investigations on ubend samples of sensitized 304 austenitic stainless steel have been conducted in sulfurous acid solutions in the concentration range, 0. Stress corrosion cracking scc of duplex stainless steel. Type 304 stainless steel an overview sciencedirect topics. Stress corrosion cracking british stainless steel association. The type of cracking observed was a function of the degree to which the specimens were sensitized.
When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. Austenitic steels of type astm 304 and 316 austenitic steels have limited resistance to stress corrosion cracking scc, even at very low chloride contents and temperatures. Sensitization, intergranular attack, stress corrosion. In both materials, scc initiation was in transgranular mode. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Why are austenitic stainless steels more susceptible to chloride stress corrosion cracking than ferritic stainless steels. Why are austenitic stainless steels more susceptible to.
The effect of nitrogen on stress corrosion cracking of aisi 304 stainless steei in hightemperature sulfate solution t. Selection of stainless steels for water tank applications. Escc susceptibility depends on environmental factors. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Stress corrosion cracking scc is characterized by cracks propagating either.
There is an additional risk of stress corrosion cracking scc at higher temperatures. Cracks were located mainly at positions close to the weld joint and the arc where very strong tensile residual stress existed. Potential and strain rate effects in slow strain rate. Stress corrosion cracking facts and how to reduce the risk. In addition to pitting, 304 stainless steel is prone to scc. A strain rate of 5 x 10sup 4 minutesup 1 was employed. Chloride stress corrosion cracking clscc is one the most common reasons. Inhibition of stress corrosion cracking in 304 stainless steel through. Sensor requirements for detection and characterization of. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. The effect of nitrogen on stress corrosion cracking of aisi. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern.
I have been reading into stress corrosion cracking scc caused by chlorides, which i understand can be quite an issue. For austenitic stainless steels, stress corrosion cracks. Irradiationinduced stress corrosion cracking of austenitic stainless steels. The effect of nitrogen on stress corrosion cracking of. It is not practical to pick one of the factors as the dominant reason for crack development. The combination of tensile stress and a specific corrosive environment can crack stainless steels. Unexpected corrosion of stainless steel in high solids black. This results because of their similarity in nickel content. Igscc susceptibilities of the bwr components could not be correlated with segregation of impurities on grain boundaries. The most essential characteristic of stainless steel is its corrosion resistance.
Chloride stress corrosion cracking in austenitic stainless. It has much less toughness than annealed 304 but it is right up there with the other hard stainless steel tube. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. When sulfides are present in caustic solutions the scc has been reported to occur at lower temperatures. It occurs in austenitic stainless steel under tensile stress in. Anodic protection is possible only for materialenvironment combinations.
The potential for stress corrosion cracking scc of welded stainless steel interim storage containers for spent nuclear fuel snf has been identified as a high priority data gap. Integral to johns manville thermo1200 and to sproule wr1200 is xox corrosion inhibitor, a distinctive formula and process that inhibits corrosion to the outside surfaces of pipe and equipment, especially stress corrosion cracking of austenitic stainless steel. This diagram figure 1 is analogous to a similar diagram for caustic. Super duplex and super austenitic stainless steels are considered virtually immune to chloride stress cracking. Polythionic stress corrosion cracking of stainless steel tube. Isaacs the stress corrosion cracking of a sensitized type 304 stainless steel has been studied at room. This work explores the fate of the coupling current generated during stress corrosion cracking of sensitized type 304 stainless steel 304ss in thiosulfate solution at ambient temperature. Normally 50 deg c but can occur at lower temperatures around 25 deg c in specific environments, notably swimming pools. Mar 11, 2020 this research was focused on the failure analysis of a cracked ss304 stainless steel elbow from a chemical plant. Effects of marine environments on stress corrosion.
The stress corrosion cracking scc of a commercial austenitic stainless steel type 304 was investigated as functions of chloride concentration, chromate concentration and test temperature under a constant applied stress condition in 0. Chlorides are problematic with austenitic stainless steels like 304 as they can cause pitting, crevice corrosion, and stress corrosion cracking. Bstype 430 stainless steel ubend specimens are not susceptible to stress corrosion cracking when stressed and exposed to an enviroment containing up to 100% osub 2, chloride concentrations to 1,100 ppm cl, ph adjusted to 11. This limits the usefulness of austenitic stainless steel for containing water with higher than a few ppm content of chlorides at temperatures above 50 c. The stress corrosion cracking susceptibility of aisi types 304 and 316 ss tubes with different heat treatments were investigated in lithiated water at 350c.
Austenitic stainless steels are widely used as structural materials for chemical and power plants. Stainless steel produces a brittle cracking phenomenon below the strength limit when a. These characteristics are consistent with stress corrosion cracking due to polythionic acids. Therefore, the scc concerns for spent fuel storage canisters identified in a november 2004 presentation by nuclear and. Although no stainless steel grade is totally immune. Corrosion of this type has been extensively studied and affects almost all metal alloys, including the austenitic grades of stainless steel used in brewing. Stress corrosion cracking is a general term describing stressed alloy failures appearing as cracks in the stainless steel that occur in corrosive environments. The effects of dissolved oxygen content in the water, heat treatment, especially slight sensitization, and most importantly chloride ion concentration on the susceptibility of type 304 stainless steel to stress corrosion cracking scc were investigated. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion.
There is also a problem with stress corrosion cracking in. Austenitic stainless steels such as types 304 and 316 are susceptible to intergranular corrosion igc and intergranular stress corrosion cracking igscc when heat treated at temperatures in the range of 450sup 0 to 850sup 0c. Stress corrosion cracking susceptibility of irradiated type. Influence of high temperature on corrosion behavior of 304. The earliest incidents of irradiation assisted stress corrosion cracking iascc in bwrs occurred during the early 1960s and were associated with cracking of type 304 stainless steel fuel cladding, where the driving forces for cracking were the increasing tensile hoop stress in the cladding due to the swelling fuel and the highly oxidizing. Stress corrosion cracking of 304l stainless steel in molten salts media.
Stress corrosion cracking of a 304 stainless steel elbow. The micrograph on the left x300 illustrates scc in a 316 stainless steel chemical processing piping system. Stress corrosion cracking susceptibility of 304l substrate and. The microscopic effects of ion implantation were evaluated by stopping and range of ions in matter procedures srim. The methodology of the drip procedure of the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as it applies to the.
Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. Pdf stress corrosion cracking of stainless steel components in. External stress corrosion cracking escc by sea salt particles can occur in these plant component materials. Influence of high temperature on corrosion behavior of 304 stainless steel in chloride solutions. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion.
The paper discusses stress corrosion cracking scc of stainless steel. Influence of chromium depletion on intergranular stress. The duplex stainless steels were developed to exhibit comparable general corrosion resistance as 316ss, but with reduced susceptibility to chloride stress corrosion cracking. Thierry, lowtemperature stress corrosion cracking of stainless steels in the atmosphere in the presence of chloride. We examined the effects of temperature and humidity on escc experimentally. This mode of attack is termed stress corrosion cracking scc. The cracks are intergranular and narrow with no significant branching. Effect of cold work on stress corrosion cracking behavior of. The failure cracks propagated from intergranular pickling damage to the 12inchthick steel, which was sensitized during initial fabrication. Stress corrosion cracking of aisi 304 and 316 stainless. Influence of high temperature on corrosion behavior of 304 stainless steel in chloride solutions aip advances. The influence of chloride concentration and acidity on the occurrence of stress corrosion cracking s. Stress corrosion cracking scc is a common issue with many specialty alloys.
Chloride stress corrosion cracking and 316 stainless steel. Stainless steels are more resistant to general corrosion compared with carbon steel. Chloride induced stress corrosion cracking of type 304 and. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of. All of the cracks observed were found underneath the coke deposits. Hard worked 304 high hardness and strength with pretty good corrosion resistance are available in heavily cold worked type 304. Stress corrosion cracking of sensitized 304 austenitic. Pitting corrosion has been reported from household bleach spills on stainless steel 304 type sinks in domestic environments. It forms when the material is subjected to tensile stress and some kinds of corrosive environments, especially chloriderich environments sea water at higher temperatures. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances.
Stress corrosion cracking of sensitized type 304 stainless steel in high temperature chloride solutions l. Insitu monitoring of stress corrosion cracking of 304. It is concluded that stress corrosion cracking was the main reason for the cracking of the elbow. Slow strain rate tests ssrts were conducted on solution annealed and sensitized aisi 304 stainless steels sss with varying nitrogen and carbon contents to study their susceptibility to stress corrosion cracking scc. Is there anything you can do to 316 stainless steel to make it acceptable for use in a chloride environment, or is it just recomended to avoid 316 stainless steel in this application. Chloride stress corrosion cracking in austenitic stainless steel. Irradiationinduced stress corrosion cracking of austenitic.
Facts in brief about stress corrosion cracking scc stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly. Effects of temperature and humidity on atmospheric stress. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Chloride stress corrosion cracking inspectioneering. The required tensile stresses may be in the form of directly applied stresses or in the form of residual.